Understanding the Reactivity of Neutral Geminal Group 14 Ele…
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- DOI 10.1021/acs.jpca.9b08573
- PMID https://pubmed.ncbi.nlm.nih.gov/31689361
- OpenAlex ID W2983171546
- Type Article
- Language EN
- Published 05 Nov 2019
- Volume 123 (46)
- Pages 10095–10101
- Source The Journal of Physical Chemistry A
- Publisher American Chemical Society
- FWCI 1.21
- Countries 1
- Institutions 2
- Added 10 Oct 2025
- Updated 22 Oct 2026
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Understanding the Reactivity of Neutral Geminal Group 14 Element/Phosphorus Frustrated Lewis Pairs
Article 2019 EN
The influence of the nature of the group 14 elements (E = Si, Ge, Sn) on the reactivity of (F 5 C 2 ) 3 E–CH 2 –P( t Bu) 2 geminal frustrated Lewis pairs (FLPs) has been computationally explored by means of density functional theory calculations. To this end, the experimentally described activation reactions of CO 2 and phenyl isocyanate have been investigated and compared to the analogous process…
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2
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1.21
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2 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | Jorge Juan Cabrera‐Trujillo | Universidad Complutense de Mad… (ES) ORFEO-CINQA Research Network (ES) | |
| 2 | Israel Fernández Corresponding | Universidad Complutense de Mad… (ES) ORFEO-CINQA Research Network (ES) |
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