Reversible Binding of Molecular Oxygen to Catecholate and Am…

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Reversible Binding of Molecular Oxygen to Catecholate and Amidophenolate Complexes of SbV: Electronic and Steric Factors

Article 2012 EN

Edge of reactivity: The reactions of reversible binding of molecular oxygen to catecholate and amidophenolate complexes of Sb(V) are investigated by analyzing the position of electronic (E(HOMO)) and steric (G-parameter) factors. The optimal electronic and steric parameters for such type reactions are found.

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1 Georgy K. Fukin Corresponding Russian Academy of Sciences (RU) G.A. Razuvaev Institute of Org… (RU)
2 E.V. Baranov Russian Academy of Sciences (RU) G.A. Razuvaev Institute of Org… (RU)
3 Andrey I. Poddel’sky Russian Academy of Sciences (RU) G.A. Razuvaev Institute of Org… (RU)
4 Vladimir K. Cherkasov Russian Academy of Sciences (RU) G.A. Razuvaev Institute of Org… (RU)
5 Gleb A. Abakumov Russian Academy of Sciences (RU) G.A. Razuvaev Institute of Org… (RU)

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