Palladium-Catalyzed Decarbonylative Borylation of Benzylic A…
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- DOI 10.1021/acs.joc.5c00823
- PMID https://pubmed.ncbi.nlm.nih.gov/40693991
- OpenAlex ID W4412570707
- Type Article
- Language EN
- Published 22 Jul 2025
- Volume 90 (30)
- Pages 10607–10615
- Source The Journal of Organic Chemistry
- Publisher American Chemical Society
- FWCI 0.89
- Countries 2
- Institutions 3
- Added 10 Oct 2025
- Updated 24 Sep 2026
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Palladium-Catalyzed Decarbonylative Borylation of Benzylic Acids for the Synthesis of Benzylboronates
Article 2025 EN
A palladium-catalyzed decarbonylative borylation of benzylic carboxylic acids by selective C-O cleavage is reported. A variety of benzylic acids bearing different functional groups are well tolerated by this method. The reaction accomplishes the synthesis of valuable pinacol benzylboronates from common benzylic acids by net decarbonylation. The key steps involve oxidative addition to the acyl C(O)…
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5 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | Feng‐Yan Zhou Corresponding | Zaozhuang University (CN) | — |
| 2 | Wenzhi Zhang | Zaozhuang University (CN) | |
| 3 | Shengjun Ni | Zaozhuang University (CN) | |
| 4 | Michal Szostak Corresponding | Rutgers, The State University … (US) | |
| 5 | Chengwei Liu Corresponding | Shanghai University (CN) |
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