Reactivity‐Tuning in Frustrated Lewis Pairs: Nucleophilicity…
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- DOI 10.1002/chem.201701080
- PMID https://pubmed.ncbi.nlm.nih.gov/28370848
- OpenAlex ID W2597677519
- Type Article
- Language EN
- Published 28 Mar 2017
- Volume 23 (31)
- Pages 7422–7427
- Source Chemistry - A European Journal
- Publisher Wiley
- FWCI 2.35
- Countries 1
- Institutions 1
- Added 10 Oct 2025
- Updated 15 Sep 2026
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Reactivity‐Tuning in Frustrated Lewis Pairs: Nucleophilicity and Lewis Basicity of Sterically Hindered Phosphines
Article 2017 EN
Abstract The nucleophilicity and Lewis basicity of sterically hindered phosphines, widely used in catalysis and in frustrated Lewis pair (FLP) chemistry, have been quantified by determining the rates and equilibrium constants of their associations with reference systems (benzhydrylium and tritylium ions) of calibrated electrophilicities and Lewis acidities. These structure–reactivity investigation…
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5 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | Elsa Follet | Ludwig-Maximilians-Universität… (DE) | — |
| 2 | Péter Mayer | Ludwig-Maximilians-Universität… (DE) | |
| 3 | David S. Stephenson | Ludwig-Maximilians-Universität… (DE) | |
| 4 | Armin R. Ofial | Ludwig-Maximilians-Universität… (DE) | |
| 5 | Guillaume Berionni Corresponding | Ludwig-Maximilians-Universität… (DE) |
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