Torsional effects on reactivity in glycosyl transfer
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- DOI 10.1039/b106257n
- OpenAlex ID W2095030330
- Type Article
- Language EN
- Published 19 Dec 2001
- Pages 337–341
- Source Journal of the Chemical Society Perkin T…
- Publisher Royal Society of Chemistry
- FWCI 1.09
- Countries 1
- Institutions 1
- Added 10 Oct 2025
- Updated 22 Sep 2026
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Torsional effects on reactivity in glycosyl transfer
Article 2001 EN
The net effect of the four substituents on a hexapyranoside is to reduce reactivity at the anomeric centre by a factor of >107 compared with the parent tetrahydropyranyl acetal. The magnitude of the steric contribution to this factor is assessed by measuring the effect of four equatorial methyl groups on the rate of hydrolysis of 4-nitrophenyl tetrahydropyranyl acetal. Though the electronic effect…
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Authors & Affiliations
3 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | Kathryn E. S. Dean | University of Cambridge (GB) | — |
| 2 | Anthony John Kirby Corresponding | University of Cambridge (GB) | — |
| 3 | Igor V. Komarov | University of Cambridge (GB) |
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