Kinetics of Pu(IV) reduction with tert-butylhydrazine
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- DOI 10.1134/s1066362206040060
- OpenAlex ID W2080738715
- Type Article
- Language EN
- Published 01 Jul 2006
- Volume 48 (4)
- Pages 348–351
- Source Radiochemistry
- Publisher Pleiades Publishing
- Countries 1
- Institutions 1
- Added 24 Jun 2016
- Updated 28 Jul 2026
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Kinetics of Pu(IV) reduction with tert-butylhydrazine
Article 2006 EN
The rate of Pu(IV) reduction with tert-butylhydrazine in an HNO3 solution is described by the equation-d[Pu(IV)]/dt = k[Pu(IV)]2[(CH3)3CN2H 4 + ]/[H+], where k = 69.4 ⊥ 3.0 l mol−1 min−1 at 50°C. The activation energy is E = 122 ⊥ 4 kJ mol−1. Probable reaction mechanisms are discussed.
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3 authors| # | Author | Institutions | ORCID |
|---|---|---|---|
| 1 | V.S. Koltunov | "VNIINM" named after AA Bochva… (RU) | — |
| 2 | V. G. Pastushchak | "VNIINM" named after AA Bochva… (RU) | — |
| 3 | G. V. Koltunov | "VNIINM" named after AA Bochva… (RU) | — |
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